<u>Answer:</u> The correct answer is Option a.
<u>Explanation:</u>
Entropy is defined as the measurement of randomness in a system.
Entropy increases as we move from solid state to liquid state to gaseous state and it decreases as we move from gaseous state to liquid state to solid state.
From the options above:
<u>Option a:</u>
Entropy is getting decreased because liquid reactants are changing its state to solid state.
<u>Option b:</u>
In this reaction, entropy is increasing because the state is changing from liquid to gaseous state.
<u>Option c: </u>
In this reaction, entropy is increasing because the state is changing from liquid to gaseous state.
<u>Option d:</u>
In this reaction, entropy is increasing because the state is changing from solid to gaseous state.
Hence, the correct answer is Option a.