Answer:
11.31g NaClO₂
Explanation:
<em> Is given 250mL of a 1.60M chlorous acid HClO2 solution. Ka is 1.110x10⁻². What mass of NaClO₂ should the student dissolve in the HClO2 solution to turn it into a buffer with pH =1.45? </em>
It is possible to answer this question using Henderson-Hasselbalch equation:
pH = pKa + log₁₀ [A⁻] / [HA]
<em>Where pKa is -log Ka = 1.9547; [A⁻] is the concentration of the conjugate base (NaClO₂), [HA] the concentration of the weak acid</em>
You can change the concentration of the substance if you write the moles of the substances:
[Moles HClO₂] = 250mL = 0.25L×(1.60mol /L) = <em>0.40 moles HClO₂</em>
Replacing in H-H expression, as the pH you want is 1.45:
1.45 = 1.9547 + log₁₀ [Moles NaClO₂] / [0.40 moles HClO₂]
-0.5047 = log₁₀ [Moles NaClO₂] / [0.40 moles HClO₂]
<em>0.3128 = </em>[Moles NaClO₂] / [0.40 moles HClO₂]
0.1251 = Moles NaClO₂
As molar mass of NaClO₂ is 90.44g/mol, mass of 0.1251 moles of NaClO₂ is:
0.1251 moles NaClO₂ ₓ (90.44g / mol) =
<h3>11.31g NaClO₂</h3>
Answer:
See the explanation
Explanation:
In this case, in order to get an <u>elimination reaction</u> we need to have a <u>strong base</u>. In this case, the base is the phenoxide ion produced the phenol (see figure 1).
Due to the resonance, we will have a more stable anion therefore we will have a less strong base because the negative charge is moving around the molecule (see figure 2).
Finally, the phenoxide will attack the <u>primary carbon</u> attached to the Cl. The C-Cl bond would be broken and the C-O would be produced <u>at the same time</u> to get a substitution (see figure 1).
To determine the amount of a certain element in a compound, we use the ratio of the elements from the compound. We calculate is follows:
45.0 g CCl4 ( 1 mol CCl4 / 153.82 g CCl4 ) ( 1 mol C / 1 mol CCl4 ) ( 12.01 g C / 1 mol C ) = 3.5135 g carbon present
Hope this answers the question. Have a nice day.
We can use the combined gas law equation to solve for the initial volume
parameters for the first instance are on the left side and parameters for the second instance are on the right side of the equation
substituting the values in the equation
V = 8.50 L
the initial volume is 8.50 L